I am sure that there are Acura dealerships that have never had an NSX through their doors. Unless you already have a line on a local NSX specialist or a dealership with a proven track record, get a service manual and be prepared to do much of your own work.
Old Guy highlighted an important note. Yes, most general maintenance items are easy for the DIY such as changing the oil or spark plugs. However, there will be others where you want an expert to help out such as replacing the coolant hoses or clutch.
Since you are in the market, I highly suggest looking for any local shops that specializes in NSX. If you like, you can even ask the shop to see if they know of any that are for sale. As Old Guy has mentioned, there is a small population of NSXs and the shop probably knows most of the local owners.
Speaking of specialized shops, it is key to find someone who can perform a proper PPI. When I was shopping for mine, finding a shop to perform a PPI was a challenge. It was not the end of the world, but I really wanted an expert opinion and someone who is familiar with the common issues of a NSX would be helpful. Obviously, any shop can check the general things such as brakes, clutch, compression, etc but there are others such as slow moving windows, gas shocks for the trunk, and the electronics issues that Old Guy already mentioned. (I think there is a wiki page with a "watch-out" list) If these are noted during the PPI, they can help you with negotiating a fair price to the seller.
Lastly, finding parts. I may sound like a broken record to Old Guy's response, but I want to share one of my experiences. I needed to replace my coil packs. Seems like a simple item to order, right? Little did I know, I could only source 3 of the 6. Eventually, I found the other 3, but they had to be sourced from Japan. Perhaps my choice in dealerships limited parts availability, but wanted to highlight that parts can be difficult to come by.
Thankfully, we have shops like Science of Speed that do supply some OEM parts. They also have some of their own aftermarket replacements. I mentioned SOS because they saved me a few times when I needed to source parts that I could not find at the dealership such as the clutch slave hose.
Good luck with your car hunt.