And for those with experience running ECU's tuned for Japanese 100 RON octane premium fuels, will running straight 93 AKI be too lean? My NA1 3.0L is stock. Thanks for any wisdom that anyone can pass on!
Octane does not directly enter into considerations of, or affect the optimum air/fuel ratio. Octane determines the resistance to detonation and detonation is determined by combustion pressures and temperatures. The factor which usually drives the need for a higher octane is an increase in peak combustion pressure typically associated with increasing the compression ratio. Camshaft selection can also clearly influence the peak combustion pressure.
Some individuals may reduce the air/fuel ratio to reduce combustion temperatures to reduce the risk of detonation in the absence of sufficiently / impossibly high octane fuel. Dropping peak cylinder pressures and temperatures by over fueling is usually a counter productive bodge to fix a problem with getting over enthusiastic with setting the compression ratio.
If you trust in the knock sensors the ECU will retard the ignition timing if it senses detonation with the 93 R+M/2. That should leave you safe. Of course, if the ECU is retarding the ignition timing (potentially back to the OEM settings?) then you have to ask 'why bother with the ignition remapping in the ECU'. The reason that individuals do not report problems running 93 R+M/2 on remapped ECUs may be that the knock sensors are retarding timing to avoid problems. Personally, I think running an engine using the knock sensors to set advance limits is a bad idea. I favor running a safe no detonation ignition map with the knock sensors as back up. If you are going to operate using the knock sensors to set the timing limits then you would want to make sure that your 1991 knock sensors are in good condition and that the ECU memory remap didn't accidentally mess up the knock control algorithm.
If you want to achieve whatever hypothetical improvements are associated with the ignition remap, you are going to have to run higher octane fuel. I am sure that the fuel chemists have their empirical models; but, in general all octane ratings used to be confirmed by testing in a designated test engine. If it detonated, they would fiddle with the fuel components to eliminate detonation. So, I am not aware of a well defined empirical method for forecasting how an octane booster will affect a fuel's octane rating. Also, to complicate things, vendors may sell 93 R+M/2; but, those fuels may use different fuel blends to achieve the target octane rating in the test engine. Because of the different fuel blends, adding octane booster to give you 95 in one vendors fuel may not give you 95 in a different vendors fuel.
If you want to experiment with octane enhancers, I suggest Toluene. Toluene is already in the fuel because most refiners already use it as an octane enhancer. It has an R+M/2 value of 114. Its best feature is that it is generally much much cheaper than octane enhancers that you can purchase from auto supply stores. You should be able to source it from industrial or paint vendors in 1 or 4 gallon cans for less than $40 per gallon. You used to be able to find sources on the internet which purport to have an empirical guide to predict octane boost versus the amount of toluene added.
Toluene or other octane enhancers may work. However, from my perspective having to add a dose of octane enhancer every time I fueled up would get old pretty quickly. As a final note, my recollection is that toluene (and I expect the other octane enhancers) are not clear coat friendly. The clear coat 'safer' way to fuel is you dilute the toluene in a couple of gallons of fuel and then add that to the tank. Way too much work.