If the "overflow bottle" (reservoir) is actually overfull, when coolant is released from the radiator to the reservoir, some coolant will be expelled into the engine compartment. Since coolant is not all water, this makes a mess of your engine compartment.
After running hot the reservoir will appear overfull until the engine fully cools. So check it when it is cold.
You should be a little suspicious of an overfull reservoir if you do not know why it has too much coolant. I have never seen it, but some radiator cap failures can block the return of water to the engine. Seen once... the coolant froze in the return tube after a hard run uphill in very cold, causing the engine to overheat running downhill from the pass. But hell that was an Alfa; anything can happen in an Alfa.